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91.
92.
Kovaleva V. V. Kuznetsov N. M. Vdovichenko A. Yu. Zagoskin Y. D. Grigoriev T. E. Chvalun S. N. 《Doklady Physical Chemistry》2022,502(2):23-27
Doklady Physical Chemistry - The rheological behavior of a 1 wt % suspension of highly porous chitosan particles in polydimethylsiloxane in a high electric field has been studied as a function of... 相似文献
93.
Turdybekov K. M. Nurkenov O. A. Seilkhanov T. M. Fazylov S. D. Turdybekova Ya. G. Kudusov A. S. 《Journal of Structural Chemistry》2022,63(6):944-950
Journal of Structural Chemistry - N-cyanomethylanabasine is prepared with an yield of 70% by the interaction of the alkaloid anabasine with glyconitrile. It is shown that the highest yield of the... 相似文献
94.
Botnar A. A. Bychkova A. N. Domareva N. P. Tikhomirova T. V. Vashurin A. S. 《Journal of inclusion phenomena and macrocyclic chemistry》2022,102(3-4):303-311
Journal of Inclusion Phenomena and Macrocyclic Chemistry - Novel neodymium phthalocyaninates based on template condensation of 4-[(4-benzyloxy)phenoxy]- or... 相似文献
95.
Ya-Shan Huang Yuan Xue Prof. Alvaro Muñoz-Castro Prof. Dr. Ivan A. Popov Prof. Dr. Zhong-Ming Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(62):e202202192
During the past two decades, single-atom-centered medium-sized germanium clusters [M@Gen] (M=transition metals, n>12) have been extensively explored, both from theoretical perspectives and experimental gas-phase syntheses. However, the actual structural arrangements of the Ge13 and Ge14 endohedral cages are still ambiguous and have long remained an unresolved problem for experimental implementation. In this work, we successfully synthesize 13-/14-vertex Ge clusters [Nb@Ge13]3− ( 1 ) and [Nb@Ge14]3− ( 2 ), which are structurally characterized and exhibit unprecedented topologies, neither classical deltahedra nor 3-connected polyhedral structures. Theoretical analysis indicates that the major stabilization of the Ge backbones arises due to the substantial interaction of Ge 4p-AOs with the endohedral Nb 4d-AOs through three/four-center two-electron bonds with an enhanced electron density accumulated over the shortest Nb−Ge13 contact in 1 . Low occupancies of the direct two-center two-electron (2c–2e) Nb−Ge and Ge−Ge σ bonds point to a considerable degree of electron delocalization over the Ge cages revealing their electron deficiency. 相似文献
96.
Bodnarchuk V. I. Boulkin A. P. Kravtsov E. A. Pleshanov N. K. Syromyatnikov V. G. Ul’yanov V. A. 《Crystallography Reports》2022,67(1):50-63
Crystallography Reports - The review is devoted to the current state of affairs and prospects for development in the field of neutron reflectometry on the existing and future neutron sources in the... 相似文献
97.
Olesia I. Kucheriv Dr. Sergii I. Shylin Valerii Y. Sirenko Dr. Vadim Ksenofontov Prof. Wolfgang Tremel Dr. Ioan-Andrei Dascălu Dr. Sergiu Shova Dr. Il'ya A. Gural'skiy 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(44):e202200924
Spin-crossover complexes with multistep transitions attract much attention due to their potential applications as multi-switches and for data storage. A four-step spin crossover is observed in the new iron(II)-based cyanometallic guest-free framework compound Fe(2-ethoxypyrazine)2{Ag(CN)2}2 during the transition from the low-spin to the high-spin state. A reverse process occurs in three steps. Crystallographic studies reveal an associated stepwise evolution of the crystal structures. Multiple transitions in the reported complex originate from distinct FeII sites which exist due to the packing of the ligand with a bulky substituent. 相似文献
98.
O. Guselnikova J.P. Fraser N. Soldatova E. Sviridova A. Ivanov R. Rodriguez A.Y. Ganin P. Postnikov 《Materials Today Chemistry》2022
Covalent functionalization of 2D materials provides a tailored approach towards tuning of their chemical, optical, and electronic properties making the search for new ways to graft small molecules important. Herein, the reaction with (3,5-bis(trifluoromethyl)phenyl)iodonium salt is revealed as an effective strategy for functionalization of MoTe2 thin films. Upon decomposition of the salt, the generated radicals graft covalently as aryl-(CF3)2 groups at the surface of both metallic (1T’) and semiconducting (2H) polymorphs of MoTe2. Remarkably, the reactivity of the salt is governed by the electronic structure of the given polymorph. While the functionalization of the metallic MoTe2 occurs spontaneously, the semiconducting MoTe2 requires activation by light. The reaction proceeds with the elimination of oxide from the original films yielding the functionalized products that remain protected in ambient conditions, presenting a viable solution to the ageing of MoTe2 in air. 相似文献
99.
Butvina V. G. Kuzmin A. V. Spivak A. V. Safonov O. G. Lazarenko V. A. Dorovatovskii P. V. 《Crystallography Reports》2022,67(7):1114-1121
Crystallography Reports - The structure of a potassium compound with the chemical formula K0.90Ti5.16Cr2.94Fe2.54Mg0.87Al0.22Mn0.30O19 has been investigated by single-crystal X-ray diffraction... 相似文献
100.
Sukhikh A. S. Khranenko S. P. Zadesenets A. V. Gromilov S. A. 《Crystallography Reports》2022,67(2):143-149
Crystallography Reports - [Pd(NH3)4]3(Мо7 – хWxO24)?6H2O crystals with different Mo/W ratios have been formed as a result of the crystallization of a... 相似文献